Project Title

Toward the development of a new tris-NHC. Coordination to coinage metals

Presenters

Academic department under which the project should be listed

CSM - Chemistry and Biochemistry

Faculty Sponsor Name

Daniela Tapu

No need for this.

Abstract (300 words maximum)

Recently, there has been an incresing interest in the design of sophisticated ligands because they can provide additional functions for use in catalysis and in material science. Poly-N-heterocyclic carbenes have been used with great success for the synthesis of such ligands. This project describes the synthesis and characterization of a new such poly-NHC. The new ligand was characterized by proton and carbon NMR spectroscopy. Its coordination to two coinage metals (gold and silver) was achieved. The new complexes were characterized by NMR spectroscopy and X-ray analysis.

Project Type

Poster

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Toward the development of a new tris-NHC. Coordination to coinage metals

Recently, there has been an incresing interest in the design of sophisticated ligands because they can provide additional functions for use in catalysis and in material science. Poly-N-heterocyclic carbenes have been used with great success for the synthesis of such ligands. This project describes the synthesis and characterization of a new such poly-NHC. The new ligand was characterized by proton and carbon NMR spectroscopy. Its coordination to two coinage metals (gold and silver) was achieved. The new complexes were characterized by NMR spectroscopy and X-ray analysis.